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D(+)-Glucose

D(+)-Glucose

Basic Information

CAS No.: 50-99-7
Molecular Formula: C6H12O6
Molecular Weight: 180.16

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Product Details

D(+)-glucose ,a short form of dextrorotatory glucose, is a stereoisomer of glucose molecule, which is biologically active and whose bottom chiral carbon has its hydroxyl group (OH) located spatially to the right.  Its molecule can exist in an open-chain (acyclic) and ring (cyclic) form and has two isomers α- and β-.  It is the main source of energy in the form of ATP for living organisms.  It is naturally occurring and is found in fruits and other parts of plants in its free state.  In animals, it arises from the breakdown of glycogen in a process known as glycogenolysis.


Chemical Properties


PropertyValue
Melting point

150-152 °C(lit.)

Alpha

52.75 º (c=10, H2O, NH4OH 25 ºC)

Boiling point

232.96°C (rough estimate)

density

1.5440

bulk density

630kg/m3

refractive index

53 ° (C=10, H2O)

storage temp.

room temp

solubility

H2O: 1 M at 20 °C,  clear,  colorless

pka

pKa 12.43(H2O,t = 18,) (Approximate)

form

Crystalline Powder

color

White

PH

5.0-7.0 (25℃, 1M in H2O)

Odor

Odorless

PH Range

5.9

biological source

wheat

optical activity

[α]25/D +52.5 to +53.0°(lit.)

Water Solubility

Soluble

λmax

λ: 260 nm Amax: 0.03λ: 280 nm Amax: 0.02

Merck

14,4459

BRN

1281608

Stability:

Stable. Substances to be avoided include strong oxidizing agents. Combustible.

InChIKey

WQZGKKKJIJFFOK- DVKNGEFBSA- N

LogP

-2.490 (est)

CAS DataBase Reference

50-99-7(CAS DataBase Reference)

NIST Chemistry Reference

Glucose(50-99-7)

EPA Substance Registry System

Dextrose (50-99-7)


Safety Information

PropertyValue
Hazard symbolsXi, Xn
Hazard class codes36/37/38-63-62-46-36/38-21
Safety instructions26-36/37-24/25-53-25
WGK Germany1
RTECS numberLZ6600000
F3
Autoignition temperature500 °C
TSCATSCA listed
HS code17023051
Storage category11 - Combustible solid
Hazardous substances data50-99-7 (Hazardous Substances   Data)
ToxicityLD50 orally in Rabbit: 25800   mg/kg


Product Usage

In addition, it is used therapeutically in fluid and nutrient replacement, such as glucose syrup and glucose powder.  It can be obtained by enzymatic cleavage of starch, so there are multiple sources like sugar cane, sugar beet, corn (corn syrup), potatoes and wheat.  Today, large-scale starch hydrolysis is used to produce glucose.

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